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GÜLLÜOĞLU, ARİF NİHAT

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GÜLLÜOĞLU

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ARİF NİHAT

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2008 - 20092
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End date: 2009 × Subject: FILMS ×

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    Effect of irradiation by 140 Mev Ag11+ ions on the optical and electrical properties of polypropylene/TiO2 composite
    (ELSEVIER, 2009) GÜLLÜOĞLU, ARİF NİHAT; Qureshi, Anjum; Singh, Dolly; Singh, N. L.; Ataoglu, S.; Gulluoglu, Arif N.; Tripathi, Ambuj; Avasthi, D. K.
    Changes in the optical, structural, dielectric properties and surface morphology of a polypropylene/TiO2 composite due to swift heavy ion irradiation were studied by means of UV-visible spectroscopy, X-ray diffraction, impedance gain phase analyzer and atomic force microscopy. Samples were irradiated with 140 MeV Ag11+ ions at fluences of 1 x 10(11) and 5 x 10(12) ions/cm(2). UV-visible absorption analysis reveals a decrease in optical direct band gap from 2.62 to 2.42 eV after a fluence of 5 x 10(12) ions/cm(2). X-ray diffractograms show an increase in crystallinity of the composite due to irradiation. The dielectric constants obey the Universal law given by epsilon proportional to integral(n-1), where n varies from 0.38 to 0.91. The dielectric constant and loss are observed to change significantly due to irradiation. Cole-cole diagrams have shown the frequency dependence of the complex impedance at different fluences. The average surface roughness of the composite decreases upon irradiation. (C) 2009 Elsevier B.V. All rights reserved.
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    Dielectric properties of polymer composites filled with different metals
    (TAYLOR & FRANCIS INC, 2008) GÜLLÜOĞLU, ARİF NİHAT; Qureshi, Anjum; Mergen, Ayhan; Eroglu, Mehmet S.; Singh, N. L.; Gulluoglu, Arif
    Electrically conductive composite systems based on polyvinyl chloride (PVC) and polymethyl methacrylate (PMMA) filled with metal powders of Al and Cu have been studied. The composite preparation conditions allow the formation of a random distribution of metallic particles in the polymer matrix. Dependence of the dielectric and conductivity properties of the PVC and PMMA/fillers was studied over a broad range of frequency and volume fraction of metal fillers. The experimental results could be explained by means of the conductivity of fillers and the interface polarization between polymers and fillers. Percolation was also seen in this study when the volume fraction of conducting fillers was close to critical value, in which the composites undergo an insulator-conductor transition. The relation among the dielectric property and the fillers with different conductivity was proposed.