Publication:
Solar-hydrogen production with reduced graphene oxide supported CdxZn1-xS photocatalysts

dc.contributor.authorÖZKAYA, ALİ RIZA
dc.contributor.authorsTanisik, Irem; Uguz, Ozlem; Akyuz, Duygu; Ayaz, Rana Muhammad Zunain; Sarioglu, Cevat; Karaca, Fatma; Ozkaya, Ali Riza; Koca, Atif
dc.date.accessioned2022-03-12T16:24:34Z
dc.date.available2022-03-12T16:24:34Z
dc.date.issued2020
dc.description.abstractReduced graphene oxide (RGO)/CdxZn(1-x)S composites were firstly synthesized by thermal sulfurization method in one pot with elemental sulfur as sulfur source. By using one pot synthesis, CdxZn(1-x)S particles were decorated on the RGO sheets during sulfurization of Cd2+ and Zn2+ precursors. This synthesis method eased the control of the particle sizes of CdxZn(1-x)S by providing homogenous decoration of RGO with CdxZn(1-x)S particles and increased the strength between RGO sheet and CdxZn(1-x)S particles, which enhanced charge carrier mobility rate. Here, RGO in the composite structure supplied high electron conductivity, high adsorption capacity and extended light absorption ability. Thus, prepared RGO/CdxZn(1-x)S composites enhanced the photocatalytic activity. The crystal systems, lattice parameters, band gaps and surface morphologies of all photocatalysts are characterized to determine the factors that affected the photocatalytic activities of the composites. After that, the photocatalytic activities of prepared photocatalysts were tested by measuring H-2 evolution rates. Among the composites, RGO/Cd0.7Zn0.3S structure possessed the highest H-2 production rate (141.6 mu molh(-1)) and apparent quantum efficiency (19.4%). (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
dc.identifier.doi10.1016/j.ijhydene.2020.04.035
dc.identifier.eissn1879-3487
dc.identifier.issn0360-3199
dc.identifier.urihttps://hdl.handle.net/11424/226385
dc.identifier.wosWOS:000609161600026
dc.language.isoeng
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD
dc.relation.ispartofINTERNATIONAL JOURNAL OF HYDROGEN ENERGY
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectGraphene
dc.subjectHydrogen production
dc.subjectPhotocatalyst
dc.subjectReduced graphene oxide (RGO)
dc.subjectSolar energy
dc.subjectSulfurization
dc.subjectIN-SITU SYNTHESIS
dc.subjectSOLID-SOLUTION
dc.subjectEFFICIENT
dc.subjectWATER
dc.subjectTEMPERATURE
dc.subjectGENERATION
dc.subjectEVOLUTION
dc.subjectNANOSTRUCTURES
dc.subjectNANOCOMPOSITES
dc.subjectNANOMATERIALS
dc.titleSolar-hydrogen production with reduced graphene oxide supported CdxZn1-xS photocatalysts
dc.typeconferenceObject
dspace.entity.typePublication
local.avesis.id1dde9d17-40a7-4be7-838c-302607fc3160
local.conference.dateJUN 20-23, 2019
local.conference.locationTrakya Univ, Edirne, TURKEY
local.conference.title4th International Hydrogen Technologies Congress (IHTEC)
local.import.packageSS15
local.indexed.atWOS
local.indexed.atSCOPUS
local.journal.numberofpages12
local.journal.quartileQ2
oaire.citation.endPage34856
oaire.citation.issue60
oaire.citation.startPage34845
oaire.citation.titleINTERNATIONAL JOURNAL OF HYDROGEN ENERGY
oaire.citation.volume45
relation.isAuthorOfPublication468ce3fe-dca4-4fd4-a890-3a220c85c8c9
relation.isAuthorOfPublication.latestForDiscovery468ce3fe-dca4-4fd4-a890-3a220c85c8c9

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