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1:1 binary complexes of citric acid with some metal ions: Stability and thermodynamic parameters

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dc.contributor.authorsBastuǧ A.S., Göktürk S., Şişmanoǧlu T.
dc.date.accessioned2022-03-15T01:56:02Z
dc.date.available2022-03-15T01:56:02Z
dc.date.issued2007
dc.description.abstractThe stability constants of the 1:1 binary complexes of citric acid with Cu2+, Ni2+, Co2+, Mn2+ and Ce 3+ were determined potentiometrically at 15.0, 25.0, and 35.0°C and at an ionic strength of 0.10 mol L-1 (NaClO4). UV-VIS spectroscopic studies were also performed in order to confirm the complexes formation and the stability constants of Cu-citric acid system determined potentiometrically. The thermodynamic parameters, ΔG°, ΔH°, and ΔS° were reported for the complexes formation reactions. The enthalpy and entropy changes of all binary complexes are positive.
dc.identifier.doi10.1515/REVIC.2007.27.1.53
dc.identifier.issn1934929
dc.identifier.urihttps://hdl.handle.net/11424/246820
dc.language.isoeng
dc.publisherFreund Publishing House Ltd
dc.relation.ispartofReviews in Inorganic Chemistry
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.title1:1 binary complexes of citric acid with some metal ions: Stability and thermodynamic parameters
dc.typearticle
dspace.entity.typePublication
local.import.packageSS21
local.import.sourceScopus
local.indexed.atSCOPUS
oaire.citation.endPage65
oaire.citation.issue1
oaire.citation.startPage53
oaire.citation.titleReviews in Inorganic Chemistry
oaire.citation.volume27

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