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TUĞTAŞ KARNABAT, ADİLE EVREN

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TUĞTAŞ KARNABAT

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ADİLE EVREN

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Now showing 1 - 3 of 3
  • Publication
    Extent of bioleaching and bioavailability reduction of potentially toxic heavy metals from sewage sludge through pH-controlled fermentation
    (PERGAMON-ELSEVIER SCIENCE LTD, 2021) TUĞTAŞ KARNABAT, ADİLE EVREN; Yesil, Hatice; Molaey, Rahim; Calli, Baris; Tugtas, Adile Evren
    Utilization of anaerobically stabilized sewage sludge on arable lands serve as a renewable alternative to chemical fertilizers as it enables recycling of valuable nutrients to food chain. However, probable pres-ence of heavy metals in sewage sludge restricts the use of stabilized sludge on lands. In this study, a novel approach based on pH-controlled fermentation and anaerobic metal bioleaching was developed to reduce ecotoxicity potential of fermented sludge prior to its land application. Sewage sludge was sub-jected to pH-controlled fermentation process at acidic, neutral, and alkaline pH levels with the aim of increasing metal solubilization and decreasing bioavailable metal fractions through anaerobic bioleaching. Alkaline reactor performed the best among all reactors and resulted in 3-fold higher hydrolysis (34%) and 6-fold higher acidification (19%) efficiencies along with 43-fold (in average) higher metal solubiliza-tion than that of neutral pH reactor. As a result of alkaline fermentation, 32-57% of the metals remained as bioavailable and 34-59% of the metals were encapsulated as non-bioavailable within solid fraction of fermented sludge (biosolid), whereas 8-12% of total metal was solubilized into fermentation liquor. Our results reveal that anaerobic bioleaching through alkaline fermentation enables biosolid production with less metal content and low bioavailability, facilitating its utilization for agricultural purposes. (c) 2021 Elsevier Ltd. All rights reserved.
  • Publication
    Removal and recovery of heavy metals from sewage sludge via three-stage integrated process
    (PERGAMON-ELSEVIER SCIENCE LTD, 2021) TUĞTAŞ KARNABAT, ADİLE EVREN; Yesil, Hatice; Molaey, Rahim; Calli, Baris; Tugtas, Adile Evren
    Heavy metal contamination of sewage sludge is one of the concerns preventing its land application. Traditional processes applied for stabilization of sewage sludge are still inadequate to serve sustainable solutions to heavy metal problem. In this study, fermentation and bioleaching potentials of sewage sludge were investigated in anaerobic reactors for either non-pretreated or ultrasonicated sludge at three different pH regimes (free of pH regulation, acidic, and alkaline). The results of the study revealed that combination of ultrasonication pretreatment and alkaline fermentation performed the best among the other cases, resulting in 33.7% hydrolysis, 10.5% acidification, 11-33% metal leaching, and up to 25% reduction in bioavailability of potentially toxic heavy metals. Bioleaching effluent obtained from the best performing reactor was subjected to membrane-based metal recovery. A supported liquid membrane impregnated with a basic carrier successfully recovered soluble metals from the bioleaching effluent with an efficiency of 39-68%. This study reveals that the proposed three-stage process, ultrasonication pretreatment-alkaline fermentation-supported liquid membrane, effectively produces stable sludge with reduced heavy metal toxicity and recovers metals from organic waste streams. (C) 2021 Elsevier Ltd. All rights reserved.
  • Publication
    Recovery of volatile fatty acids via membrane contactor using flat membranes: Experimental and theoretical analysis
    (PERGAMON-ELSEVIER SCIENCE LTD, 2014) TUĞTAŞ KARNABAT, ADİLE EVREN; Tugtas, Adile Evren
    Volatile fatty acid (VFA) separation from synthetic VFA solutions and leachate was investigated via the use of a membrane contactor. NaOH was used as a stripping solution to provide constant concentration gradient of VFAs in both sides of a membrane. Mass flux (12.23 g/m(2) h) and selectivity (1.599) observed for acetic acid were significantly higher than those reported in the literature and were observed at feed pH of 3.0, flow rate of 31.5 +/- 0.9 mL/min, and stripping solution concentration of 1.0 N. This study revealed that the flow rate, stripping solution strength, and feed pH affect the mass transfer of VFAs through the PTFE membrane. Acetic and propionic acid separation performances observed in the present study provided a cost effective and environmental alternative due to elimination of the use of extractants. (C) 2014 Elsevier Ltd. All rights reserved.