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TUĞTAŞ KARNABAT, ADİLE EVREN

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TUĞTAŞ KARNABAT

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ADİLE EVREN

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Now showing 1 - 4 of 4
  • Publication
    Removal of heavy metals from leaching effluents of sewage sludge via supported liquid membranes
    (ELSEVIER, 2019) TUĞTAŞ KARNABAT, ADİLE EVREN; Yesil, H.; Tugtas, A. E.
    Heavy metal content of sewage sludge is one of the factors preventing its agricultural use. Leaching processes have been used to solubilize heavy metals and thus reduce metal content of the sludge through chemical or biological routes. Subsequent to leaching processes, metal removal from the supematant is attractive in terms of decreasing metal content of the effluent and recovering metals. This paper investigates application of supported liquid membrane (SLM) technology for metal removal from leaching effluents. SLM system was first optimized using synthetic metal mixtures. Optimized system was then used for the anaerobic bioleaching and chemical leaching effluents and metal removal efficiencies of 27.1 +/- 1.3% and 46.0 +/- 4.3% were obtained, respectively. Considering integrated leaching and membrane separation processes, metal removal efficiencies obtained in this study are valuable as it will decrease the metal content of sludge and increase the metal solubilization during leaching process. Future integration of metal leaching and removal technologies would make it possible to develop a sustainable system involving heavy metal removal from sewage sludge, land application of the sludge with a low metal content, and metal recovery. (C) 2019 Elsevier B.V. All rights reserved.
  • Publication
    Recovery of mixed volatile fatty acids from anaerobically fermented organic wastes by vapor permeation membrane contactors
    (ELSEVIER SCI LTD, 2018) TUĞTAŞ KARNABAT, ADİLE EVREN; Aydin, Senem; Yesil, Hatice; Tugtas, A. Evren
    Volatile fatty acids (VFAs) are attractive compounds in renewable based bio-refinery industries and can be produced through anaerobic digestion of organic wastes. Nevertheless, the recovery of VFAs from anaerobically digested organic wastes is the bottleneck of the resource recovery. In this study, VFA recovery from synthetic VFA solutions and fermented organic wastes via air-filled and tertiary amine extractant-filled PTFE membranes through vapor pressure membrane contactors (VPMC) was investigated. Acetic acid was recovered with greater than 45% efficiency in all the fermented wastes. Recovery of propionic, butyric, valeric, and caproic acids through trioctylamine-filled PTFE membrane was greater than 86% and 95% from landfill leachate and fermentation broth of anaerobically digested organic waste, respectively. This study reveals that VFA separation can be effectively achieved via economic and environmental friendly VPMC system and the process is implementable as it can be coupled to a fermentation process to prevent inhibition and to recover VFAs.
  • Publication
    A hybrid dry-fermentation and membrane contactor system: Enhanced volatile fatty acid (VFA) production and recovery from organic solid wastes
    (PERGAMON-ELSEVIER SCIENCE LTD, 2021) TUĞTAŞ KARNABAT, ADİLE EVREN; Yesil, Hatice; Calli, Baris; Tugtas, Adile Evren
    Anaerobic dry-fermentation of food wastes can be utilized for the production of volatile fatty acids (VFA). However, especially for high load fermentation systems, accumulation of VFAs may result in inhibition of fermentation process. In this study, separation of VFAs from synthetic mixtures via a vapor permeation membrane contactor (VPMC) system with an air-filled polytetrafluoroethylene (PTFE) membrane was assessed at various temperatures and permeate solution concentrations. In addition, a pioneering integrated leach-bed fermentation and membrane separation system was operated with undefined mixed culture for the purpose of enhanced VFA production along with its recovery. Hybrid system resulted in 42% enhancement in total VFA production and 60% of total VFAs were recovered through the VPMC system. The results of this study revealed that integrated system can be exploited as a means of increasing organic loading to fermentation systems and increasing the value of VFA production. (c) 2021 Elsevier Ltd. All rights reserved.
  • Publication
    Pervaporative Separation of Mixed Volatile Fatty Acids: A Study Towards Integrated VFA Production and Separation
    (SPRINGER, 2020) TUĞTAŞ KARNABAT, ADİLE EVREN; Yesil, Hatice; Taner, Hatice; Nigiz, Filiz Ugur; Hilmioglu, Nilufer; Tugtas, A. Evren
    Volatile fatty acids (VFAs) are heavily synthesized from fossil-based processes regardless of the scarcity of non-renewable resources. Anaerobic fermentation of organic wastes can be an alternative way to produce VFAs, however the recovery of VFAs from fermentation broths is the bottleneck of the resource recovery. In this study, membrane contactor based pervaporation system was used to recover VFAs through polytetrafluoroethylene (PTFE), tridodecylamine (TDDA) filled PTFE, and composite silicone rubber/PTFE membranes. Synthetic VFA mixtures were used as feed solutions representing fermentation broths composed of acetic, propionic, butyric, valeric, and caproic acids. Effect of temperature on recovery of VFAs through PTFE and TDDA filled PTFE liquid membrane was investigated at 21 degrees C, 35 degrees C, and 55 degrees C. In addition, effect of increased membrane thickness on VFA recovery efficiency of composite membranes was assessed at 35 degrees C. The results of the study revealed that TDDA filled PTFE liquid membrane resulted in significantly higher VFA flux, separation factor, permeance, and selectivity compared to that of PTFE membrane, which was presumably due to strong ion-pair formation between TDDA and carboxylic acids. The highest permeance of VFAs were observed at 35 degrees C through TDDA filled PTFE liquid membrane. Membrane thickness significantly influenced the VFA separation efficiency in composite membranes. The highest membrane selectivity of VFAs was observed in a composite membrane with 190.24.8 mu m thickness. The results of the study are significant in terms of the development of integrated fermentation and membrane-based VFA separation applications, which will hopefully decrease the reliance on fossil-fuels for VFA production.