Person: MADAKBAŞ, SEYFULLAH
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MADAKBAŞ
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SEYFULLAH
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Publication Metadata only Surface and proton conductivity properties of electrospun poly(vinyl butyral)/polyaniline nanofibers(WILEY, 2018) ÇAKMAKÇI, EMRAH; Basturk, Emre; Cakmakci, Emrah; Madakbas, Seyfullah; Kahraman, Memet VezirProton-conductive electrospun nanofibers are promising potential materials for several advanced technological applications such batteries, sensors, and fuel cells. In this work, we prepared poly(vinyl butyral)/polyaniline (PVB/PANI) nanofibers via electrospinning and determined their proton conductivities. Structural characterization of the nanofibers was performed by FTIR analysis. Surface morphology of the nanofibers was determined by SEM and AFM. The addition of PANI significantly affected the fiber morphology, and over 90% reduction (with respect to neat PVB nanofibers) in the average nanofiber diameters was observed. Nanofiber mats were doped with polyphosphoric acid. The proton conductivity of the 2 wt.% PANI containing blend nanofibers was found as 18 x 10(-6) S/cm at room temperature and at 100% humidity.Publication Metadata only Preparation, characterisation, and dielectric properties of polypyrrole-clay composites(SPRINGER INTERNATIONAL PUBLISHING AG, 2013) ÇAKMAKÇI, EMRAH; Madakbas, Seyfullah; Cakmakci, Emrah; Kahraman, Memet Vezir; Esmer, KadirIn this study, polypyrrole-clay (PPy-clay) composites were prepared by the in situ chemical oxidative polymerisation of pyrrole in the presence of clay. The chemical structures of the composites were characterised by FTIR and XRD analysis. The thermal properties of these novel composites were analysed by TGA and DSC measurements. Glass-transition temperatures and char yields increased with the increase in clay content in the nanocomposites. The interactions between PPy and clay were mainly between polypyrrole and the layers of clay. It was observed that, as the amount of clay in the composites increased, the dielectric permittivity decreased while the dielectric conductivity of the composite materials increased.Publication Metadata only Preparation and Characterization of Polyaniline/Hexagonal Boron Nitride Composites(WALTER DE GRUYTER GMBH, 2013) ÇAKMAKÇI, EMRAH; Cakmakci, Emrah; Madakbas, SeyfullahPolyaniline (PANI) is one of the most studied conductive polymer with several unique properties and good conductivity. In this study it was aimed to prepare Polyaniline (PANI)/Hexagonal boron nitride (h-BN) composites. Chemical structures of the composites were characterized by FTIR analysis. Thermal properties of these novel composites were analyzed by TGA and DSC measurements. Glass transition temperatures and char yields of the composites increased with increasing h-BN percentage. FTIR, XRD and UV measurements indicated that the boron atoms in h-BN particles interact with the unpaired electrons in nitrogen atoms of PANI. Dielectric measurements revealed dipolar polarization behavior of the composites.Publication Metadata only Preparation and thermal properties of polyacrylonitrile/hexagonal boron nitride composites(ELSEVIER SCIENCE BV, 2013) ÇAKMAKÇI, EMRAH; Madakbas, Seyfullah; Cakmakci, Emrah; Kahraman, Memet VezirPolyacrylonitrile is a thermoplastic polymer with unique properties and it has several uses. However its flammability is a major drawback for certain applications. In this study it was aimed to prepare polyacrylonitrile (PAN)/hexagonal boron nitride (h-BN) composites with improved flame retardancy and thermal stability. Chemical structures of the composites were characterized by FTIR analysis. Thermal properties of these novel composites were analysed by TGA and DSC measurements. Glass transition temperatures and char yields increased with increasing h-BN percentage. Flame retardancy of the PAN composite materials improved with the addition of h-BN and the LOI value reached to 27% from 18%. Furthermore, the surface morphology of the composites was investigated by SEM analysis. (c) 2012 Elsevier B.V. All rights reserved.