Person: KAHRAMAN, MEMET VEZİR
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KAHRAMAN
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MEMET VEZİR
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Publication Metadata only Preparation and evaluation of linseed oil based alkyd paints(ELSEVIER SCIENCE SA, 2014) OKTAY, BURCU; Iseri-Caglar, Dondu; Basturk, Emre; Oktay, Burcu; Kahraman, M. VezirAlkyd resins are produced with reaction of oil or fatty oil, polyol and polyacid. Alkyd resins are commonly used in coating and paint industry due to ease of application in changing environmental conditions. Linseed oil based paints executed all requirements of technical properties, drying time, storage properties, simplicity in maintenance, appearance, economy, etc. In this study, linseed oil based alkyd resins having different oil contents were synthesized Paint formulations were prepared by mixing alkyd resin and various additives such as huntite, Aerosil R972, talc, titanium dioxide, dryer, wetting agent and anti-skinning agent. All formulations were applied on paper test plates and were dried at 30 degrees C. The obtained coatings were characterized by pencil hardness test, pendulum hardness test, chemical resistance test, cross-cut test, contact angle and gloss measurement. Also thermal and morphological properties were investigated by thermal gravimetric analysis (TGA) and scanning electron microscopy (SEM) respectively. The thermal stability of the paint materials are improved with by increasing the amount of huntite and Aerosil R972 in the paint compositions. (C) 2013 Elsevier B.V. All rights reserved.Publication Metadata only UV cured thiol-ene flame retardant hybrid coatings(ELSEVIER SCIENCE SA, 2013) OKTAY, BURCU; Basturk, Emre; Oktay, Burcu; Kahraman, Memet Vezir; Apohan, Nilhan KayamanIn this study, bis-(triethoxysilylpropyl) phenyl phosphamide (BESPPA) was synthesized by the reaction between dichlorophenyl phosphine oxide and 3-aminopropyltriethoxysilane. The chemical structure of the BESPPA was characterized with Fourier transform infrared and NMR techniques. Flame retardant, BESPPA and sol gel precursor containing hybrid materials were prepared by thiol-ene polymerization with the aim to improve their final thermal and flame retardant properties. The thermal stabilities of the phosphorous/sol-gel containing UV-cured hybrid materials were investigated by thermogravimetric analysis. The results showed that the addition of sol-gel precursor and BESPPA into the organic network also improves the thermal-oxidative stability of the hybrid materials. The flame-retardant properties of the UV-cured hybrid materials were also studied. Furthermore, the phosphorus silicon synergistic effect on LOI enhancement and increasing flame retardancy of the UV-cured hybrid materials were demonstrated. An LOI enhancement from 20.7 to 26.5 is observed for organic resins containing both phosphorus and silicon. The surface morphology was also characterized by scanning electron microscopy (SEM). SEM studies indicated that inorganic particles were dispersed homogenously throughout the organic matrix. (C) 2012 Elsevier B.V. All rights reserved.