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GÖRK, GÜLŞEN

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GÖRK

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GÜLŞEN

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    Nonlinear optical behavior and optical power limiting characteristics of peripheral symmetrical and non-symmetrical zinc phthalocyanines with nanosecond pulsed excitation
    (PERGAMON-ELSEVIER SCIENCE LTD, 2021) GÖRK, GÜLŞEN; Erdem, Murat; Korkmaz, Eda; Kosoglu, Gulsen; Ahmetali, Erem; Farajzadeh, Nazli; Eryurek, Gonul; Kocak, Makbule Burkut
    In this study, the optical nonlinear absorption and optical limiting performances of symmetrical and non-symmetrical zinc phthalocyanines in tetrahydrofuran (THF) solution were conducted by the open aperture z-scanning technique. A new non-symmetrically substituted metallophthalocyanine, namely 2(3)-[(4- nitrophenyl)ethynyl]-{9(10),16(17),23(24)-tris-(3,5-bis(trifluoromethyl)phenoxy)-phthalocyani-nato}zinc(II) (1b), was synthesized and then characterized by applying different spectroscopic methods, such as FT-IR, H-1 NMR and MALDI-TOF spectroscopy. According to the literature, {2(3),9(10),16(17),23(24)-tetrakis-(3,5-bis(trifluoromethyl)phenoxy)-phthalocyaninatolzin(II) (1a), {2,3,9,10,16,17,23,24-octakis-(3,5-bis(trifluomethyl)phenoxy)-phthalocyaninato}zinc(II) (2a) and 2(3)-[(4-nitrophenyl)ethynyl]-{9,10,16,17,23,24-hexakis-(3,5-bis(trifluoromethyl)phenoxy)-phthalocyani nato}zinc(II) (2b) were prepared. The effect of the symmetry and substituent's number on the nonlinear behavior was determined. A Nd:YAG laser, nanosecond pulsed at 532 nm, was used as the excitation source. The measurements of the input-output power and the nonlinear transmission properties were carried out for different excitation power values and different concentrations of the phthalocyanines in the THF solution. The nonlinear absorption coefficient of beta and the imaginary part of the third order nonlinear susceptibility of the medium (X-3) were found to be strongly dependent on the concentration. All the zinc phthalocyanine complexes showed good optical limiting performances, attributed to a reverse saturable absorption (RSA) process. The results indicate that the zinc phythcyanine complexes are promising candidates for optical limiting materials. (C) 2020 Elsevier Ltd. All rights reserved.
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    Nonlinear optical properties of peripheral symmetrically and non-symmetrically 4-(trifluoromethoxy)phenoxy substituted zinc phthalocyanines
    (ELSEVIER SCIENCE SA, 2020) GÖRK, GÜLŞEN; Farajzadeh, Nazli; Kosoglu, Gulsen; Erdem, Murat; Eryurek, Gonul; Kocak, Makbule Burkut
    In this work, new non-symmetrical, peripherally substituted metallophthalocyanines, namely 2(3)-[(4-nitrophenyeethynyl]-{9,10,16,17, 23, 24-hexakis-(4-(trifluoromethoxy)phenoxy)-phthalo cyaninato zinc (1 b) and 2(3)-[(4-nitrophenyeethynyl]-{9(10),16(17),23(24)-tris-(4-(trifluoromethoxy)phenoxy)-phthalocyaninatolzinc (2b) were prepared. Structural elucidation of the novel zinc phthalocyanines was carried out with well-known spectroscopic methods. The solubility of the phthalocyanines was investigated in organic solvents like tetra-hydrofuran, dichloromethane, and dimethyl sulfoxide. The effect of concentration on aggregation behavior of the resulting phthalocyanines (1b and 2b) was examined in a wide area ranging from 4 x 10(-6) to 14 x 10(-6) M in tetrahydrofuran. Aggregation properties of the macrocyclic molecules (1b and 2b) were also investigated in many organic solvents. Based on the data existing in the literature, peripherally octa- and tetra-substituted zinc phthalocyanines (1a and 2a) with 4-(trifluoromethoxy)phenoxy moieties were synthesized. Optical limiting and the third-order nonlinear properties of symmetrically and non-symmetrically substituted phthalocyanines were determined and compared with each other.