Publication: Synthesis and Characterization of Novel Zn(II) Dimeric Phthalocyanines
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Date
2009
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SPRINGER
Abstract
Starting with tetracyanodibenzo(1,4,7,10-tetrathia-(12-crown-4)) (1) and 4-nitro-1,2-dicyanobenzene (2), nitro-substituted dimeric phthalocyanine (3) was synthesized. In the second step, using hydrazine hydrate as a reductant, amine-substituted dimeric phthalocyanine (4) was synthesized from nitro-substituted dimeric phthalocyanine. Structrures of all synthesized compounds were determined by elemental analyses, UV/vis, H-1-NMR and IR spectroscopy.
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Keywords
Amine, dimeric, nitro, phthalocyanine, SANDWICH DILUTETIUM TETRAPHTHALOCYANINE, UNSYMMETRICAL PHTHALOCYANINES