Person: BİRTANE, HATİCE
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BİRTANE
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HATİCE
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Publication Metadata only Cellulose/cysteine based thiol-ene UV cured adsorbent: removal of silver (I) ions from aqueous solution(SPRINGER, 2021) BİRTANE, HATİCE; Cigil, Asli Beyler; Urucu, Oya Aydin; Birtane, Hatice; Kahraman, Memet VezirIn the present study, a novel, eco-friendly, and simple polymeric adsorbent was obtained from cellulose acetate butyrate (CAB) and cysteine (Cys) to remove silver (I) ions in the presence of a thiol-ene click reaction under UV rays. Accordingly, firstly, CAB was modified with acrylate groups to turn it into a photocurable resin. Then, the acrylate modified CAB obtained with the monomer having cysteine and triacrylate group was crosslinked by thiol-ene click reaction under UV rays to obtain an eco-friendly adsorbent. The adsorbent acquired -S-, -COO and -NH2 groups as a result of this reaction and these functional groups are known to have the ability to selectively couple with Ag(I) ions. The adsorbent was evaluated for the selective removal of Ag(I) ions from aqueous samples characterized by SEM, SEM-EDAX, and FTIR. To determine the most suitable conditions, the effect of important parameters such as pH and contact time was investigated. It was determined that the most suitable isotherm for adsorption was the Langmuir isotherm (R: 0.999). The efficacy of our eco-friendly adsorbent was investigated in a real stream and lake waters and very good results were achieved. [GRAPHICS] .Publication Metadata only Selective molecularly imprinted polymer for the analysis of chlorpyrifos in water samples(ELSEVIER SCIENCE INC, 2020) KÖK YETİMOĞLU, ECE; Urucu, Oya Aydin; Cigil, Asli Beyler; Birtane, Hatice; Yetimoglu, Ece Kok; Kahraman, Memet VezirIn this paper, a new molecularly imprinted solid-phase extraction (MISPE) method was described for the determination of the chlorpyrifos in water samples. A thiol-ene based UV-cured polymer was prepared by mixing glyoxal bis (-diallyl acetal), pentaerythritol tetrakis (3-mercaptopropionate), polyethylene glycol diacrylate (PEGDA), and photoinitiator. Chlorpyrifos was added to the prepared polymer as a template analyte, and its analysis was performed by gas chromatography with mass detection (GC-MS). The influence of some analytical parameters was studied. We found that the use of the molecularly imprinted polymer (MIP) UV-cured disc provides an easy, selective, and available solution for removing chlorpyrifos from water samples. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.Publication Open Access Production of ink containing thermochromic dyestuff(2022-01-01) AYDIN URUCU, OYA; BİRTANE, HATİCE; AYDIN URUCU O., BİRTANE H.© 2022 Authors.Security inks are functional inks containing a binder and a special colorant used in money, checks and valuable documents. In security inks, thermochromic dyes, UV emitted, infrared emitted dyes can be used. Thermochromic dyestuffs provide different colors at different temperatures and ensure the requirements in the field of security. Thermochromic inks are generally used in smart packaging applications, high temperature alarms and security inks. Thermochromic dyes are generally metal-containing chemical materials. In this study, ink will be produced for metal surfaces by using commercial thermochromic dyestuff and it will be provided to act as a temperature warning plate. For this purpose, UV spectra of the thermochromic dyestuff was determinate with different temperature. Solvent-based ink with polyurethane binder containing 1; 3; 5% commercial thermochromic substance was produced. Screen prints were made on the metal surface with the produced ink. The color and gloss properties of the prints were measured with a spectrophotometer and glossmeter, respectively, at different temperatures. Print quality and surface properties were determined with an optical microscope. In addition, alkali, nitro, acid resistance tests were carried out. The reusability (color change) number was determined depending on how many temperature changes the print has. As a result, inks that change color at 38 °C with commercial thermochromic material were produced and successfully printed.