Publication:
Selective molecularly imprinted polymer for the analysis of chlorpyrifos in water samples

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2020

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ELSEVIER SCIENCE INC

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Abstract

In this paper, a new molecularly imprinted solid-phase extraction (MISPE) method was described for the determination of the chlorpyrifos in water samples. A thiol-ene based UV-cured polymer was prepared by mixing glyoxal bis (-diallyl acetal), pentaerythritol tetrakis (3-mercaptopropionate), polyethylene glycol diacrylate (PEGDA), and photoinitiator. Chlorpyrifos was added to the prepared polymer as a template analyte, and its analysis was performed by gas chromatography with mass detection (GC-MS). The influence of some analytical parameters was studied. We found that the use of the molecularly imprinted polymer (MIP) UV-cured disc provides an easy, selective, and available solution for removing chlorpyrifos from water samples. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

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Keywords

Selective removal, Thiol-ene, Molecularly imprinted polymers, Water treatment, UV-cured polymer, SOLID-PHASE EXTRACTION, ORGANOPHOSPHORUS PESTICIDES

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