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Allyl Phosphonium Salt-Modified Clay for Photocured Coatings: Influence on the Properties of Polyester Acrylate-Based Coatings

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dc.contributor.authorÇAKMAKÇI, EMRAH
dc.contributor.authorsZeytuncu, Bihter; Cakmakci, Emrah; Kahraman, Memet Vezir
dc.date.accessioned2022-03-13T12:49:01Z
dc.date.available2022-03-13T12:49:01Z
dc.date.issued2015
dc.description.abstractIn this study, bentonite clay was modified with a phosphonium salt and this modified clay was used to prepare polyester acrylate based coatings to improve their flame retardancy and mechanical properties. Photocured composites were prepared with 1, 2, and 3 wt% phosphonium salt modified clay and for comparison 1 wt% nonmodified clay containing composites were also prepared. Modified clay displayed good dispersion properties due to its increased basal spacing. Composites were characterized by FT-IR and XRD measurements. According to XRD results, it was found that the modified clay was exfoliated in the composites. Furthermore, we investigated the effect of allyl phosphonium salt modified clay on the thermal, mechanical, and flame retardant properties of polyester acrylate based composites coatings. When compared with neat clay containing coatings, modified clay containing photocured coatings exhibited increased modulus and enhanced thermal properties due to increased crosslinking density. Moreover, the presence of the phosphonium salt enhanced the flame retardancy of the polyester based coatings. POLYM. COMPOS., 36:946-954, 2015. (c) 2014 Society of Plastics Engineers
dc.identifier.doi10.1002/pc.23015
dc.identifier.eissn1548-0569
dc.identifier.issn0272-8397
dc.identifier.urihttps://hdl.handle.net/11424/238254
dc.identifier.wosWOS:000353244100018
dc.language.isoeng
dc.publisherWILEY
dc.relation.ispartofPOLYMER COMPOSITES
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectMECHANICAL-PROPERTIES
dc.subjectNANOCOMPOSITES
dc.subjectBEHAVIOR
dc.titleAllyl Phosphonium Salt-Modified Clay for Photocured Coatings: Influence on the Properties of Polyester Acrylate-Based Coatings
dc.typearticle
dspace.entity.typePublication
local.avesis.ide684fa52-9701-48b2-ad14-f529220cb07e
local.import.packageSS17
local.indexed.atWOS
local.indexed.atSCOPUS
local.journal.numberofpages9
oaire.citation.endPage954
oaire.citation.issue5
oaire.citation.startPage946
oaire.citation.titlePOLYMER COMPOSITES
oaire.citation.volume36
relation.isAuthorOfPublication332869cd-e8a9-40ac-b678-cf5b01c6a6dc
relation.isAuthorOfPublication.latestForDiscovery332869cd-e8a9-40ac-b678-cf5b01c6a6dc

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