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Phosphorus Ester Containing Mesoporous Silica as Novel High-Effective Flame Retardant in Polyurethane and Polyester Coatings

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dc.contributor.authorKAHRAMAN, MEMET VEZİR
dc.contributor.authorsAytan, Emre; Aytan, Tugce Akbal; Kahraman, Memet Vezir
dc.date.accessioned2022-03-12T22:55:37Z
dc.date.available2022-03-12T22:55:37Z
dc.date.issued2021
dc.description.abstractIn this study mesoporous silica spheres (MPSs) and polyphosphoric acid based organophosphate ester flame retardant (FR material) material were synthesized and flame retardancy performance in acrylate-based polyurethanes (PUR) and polyester (PET) resins investigated. For this, both MPSs and FR material were synthesized according to literature and FR material was loaded into MPSs which takes the role of carrier. Loaded MPSs were put into UV curable PUR and PET resins and polymerized under UV radiation. Their characteristics were investigated by FT-IR, TGA, LOI, SEM and TEM. The results showed that FR material had excellent flame-retardant abilities for both PUR and PET series. The TGA curves suggested that synthesized FR material shows lower thermal stability at low temperatures than original materials however it showed good ability of char formation at higher temperatures, therefore improving the flame retardant property of samples. Moreover the LOI analysis showed that flame retardancy properties were improved significantly. The additive increased the LOI value from 20,5 and 21 to 26,5 and 27.
dc.identifier.doi10.1002/slct.202100708
dc.identifier.issn2365-6549
dc.identifier.urihttps://hdl.handle.net/11424/236791
dc.identifier.wosWOS:000674289000023
dc.language.isoeng
dc.publisherWILEY-V C H VERLAG GMBH
dc.relation.ispartofCHEMISTRYSELECT
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectGreen chemistry
dc.subjectMesoporous Materials
dc.subjectPhotochemistry
dc.subjectPolymers
dc.subjectTHERMAL-DEGRADATION
dc.subjectFLAMMABILITY
dc.subjectCOMPOSITES
dc.titlePhosphorus Ester Containing Mesoporous Silica as Novel High-Effective Flame Retardant in Polyurethane and Polyester Coatings
dc.typearticle
dspace.entity.typePublication
local.avesis.id97fde971-8632-429a-b0cc-8e34ed3b2d5d
local.import.packageSS17
local.indexed.atWOS
local.indexed.atSCOPUS
local.journal.numberofpages7
oaire.citation.endPage6547
oaire.citation.issue25
oaire.citation.startPage6541
oaire.citation.titleCHEMISTRYSELECT
oaire.citation.volume6
relation.isAuthorOfPublication7676f3ad-0384-4001-b17d-b928ae2de7e6
relation.isAuthorOfPublication.latestForDiscovery7676f3ad-0384-4001-b17d-b928ae2de7e6

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