Publication:
Facile Modification of Propiolated Castor Oil via Nucleophilic Thiol-Yne Click Reactions

Simple item page
dc.contributor.authorÇAKMAKÇI, EMRAH
dc.contributor.authorsKalayci D., Akar E., Lüleburgaz S., ÇAKMAKÇI E., Günay U. S., Kumbaracı İ. V., Durmaz H., Tunca Ü.
dc.date.accessioned2024-08-08T08:29:36Z
dc.date.available2024-08-08T08:29:36Z
dc.date.issued2024-01-01
dc.description.abstractThe combination of modern click protocols and bio-based building blocks is a great step toward energy-efficient, and sustainable polymer production. Herein, thiol-Michael addition (thiol-yne) reactions from the toolbox of click chemistry protocols are chosen and propiolated castor oil (PCO) is used, a vegetable oil derivative, as the bio-based building block for the facile functionalization of PCO with various thiols. In addition to the functionalization of PCO, hyperbranched and crosslinked polymers are also prepared. The thiol-yne click functionalization reactions of the PCO are conducted at room temperature within 5 min and in the presence of an organic catalyst. The yields are found to change between 80% and 99% depending on the type of the thiol compound. The effect of various organic catalysts is investigated, and 1,8-diazabicyclo(5.4.0)undec-7-ene (DBU) is found to be the most effective catalyst for the thiol-yne modification reactions. The hyperbranched polymer reaches 23.8 kDa (Mw) within 5 min. The findings of this paper open up new horizons for polymer researchers who work in the field of sustainable polymers and click chemistry and the presented idea here is appealing because it offers a potential strategy for fast, reliable, modular, and functional macromolecule preparation from renewable vegetable oils.
dc.identifier.citationKalayci D., Akar E., Lüleburgaz S., ÇAKMAKÇI E., Günay U. S., Kumbaracı İ. V., Durmaz H., Tunca Ü., "Facile Modification of Propiolated Castor Oil via Nucleophilic Thiol-Yne Click Reactions", Macromolecular Chemistry and Physics, 2024
dc.identifier.doi10.1002/macp.202400146
dc.identifier.issn1022-1352
dc.identifier.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85195669783&origin=inward
dc.identifier.urihttps://hdl.handle.net/11424/297489
dc.language.isoeng
dc.relation.ispartofMacromolecular Chemistry and Physics
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectFizik
dc.subjectYoğun Madde 1:Yapısal, Mekanik ve Termal Özellikler
dc.subjectKimya
dc.subjectBiyokimya
dc.subjectBiyoinorganik Kimya
dc.subjectFizikokimya
dc.subjectPolimer Karakterizasyonu
dc.subjectTemel Bilimler
dc.subjectMühendislik ve Teknoloji
dc.subjectPhysics
dc.subjectCondensed Matter 1: Structural, Mechanical and Thermal Properties
dc.subjectChemistry
dc.subjectBiochemistry
dc.subjectBioinorganic Chemistry
dc.subjectPhysical Chemistry
dc.subjectCharacterization of Polymers
dc.subjectNatural Sciences
dc.subjectEngineering and Technology
dc.subjectMühendislik, Bilişim ve Teknoloji (ENG)
dc.subjectTemel Bilimler (SCI)
dc.subjectMalzeme Bilimi
dc.subjectPOLİMER BİLİMİ
dc.subjectKİMYA, FİZİKSEL
dc.subjectKİMYA, ORGANİK
dc.subjectMALZEME BİLİMİ, ÇOKDİSİPLİNLİ
dc.subjectFİZİK, YOĞUN MADDE
dc.subjectEngineering, Computing & Technology (ENG)
dc.subjectNatural Sciences (SCI)
dc.subjectMATERIALS SCIENCE
dc.subjectCHEMISTRY
dc.subjectPHYSICS
dc.subjectPOLYMER SCIENCE
dc.subjectCHEMISTRY, PHYSICAL
dc.subjectCHEMISTRY, ORGANIC
dc.subjectMATERIALS SCIENCE, MULTIDISCIPLINARY
dc.subjectPHYSICS, CONDENSED MATTER
dc.subjectYoğun Madde Fiziği
dc.subjectFizik Bilimleri
dc.subjectFiziksel ve Teorik Kimya
dc.subjectPolimerler ve Plastikler
dc.subjectOrganik Kimya
dc.subjectMalzeme Kimyası
dc.subjectCondensed Matter Physics
dc.subjectPhysical Sciences
dc.subjectPhysical and Theoretical Chemistry
dc.subjectPolymers and Plastics
dc.subjectOrganic Chemistry
dc.subjectMaterials Chemistry
dc.subjectactivated alkyne
dc.subjectcastor oil
dc.subjecthyperbranched polymers
dc.subjectthiol-michael click reactions
dc.titleFacile Modification of Propiolated Castor Oil via Nucleophilic Thiol-Yne Click Reactions
dc.typearticle
dspace.entity.typePublication
local.avesis.id77f82200-ace1-4426-92da-bdebafda4ae1
local.indexed.atSCOPUS
relation.isAuthorOfPublication332869cd-e8a9-40ac-b678-cf5b01c6a6dc
relation.isAuthorOfPublication.latestForDiscovery332869cd-e8a9-40ac-b678-cf5b01c6a6dc

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
file.pdf
Size:
1.97 MB
Format:
Adobe Portable Document Format
Download

Collections

Research Outputs