Publication:
Cellulose/cysteine based thiol-ene UV cured adsorbent: removal of silver (I) ions from aqueous solution

dc.contributor.authorBİRTANE, HATİCE
dc.contributor.authorsCigil, Asli Beyler; Urucu, Oya Aydin; Birtane, Hatice; Kahraman, Memet Vezir
dc.date.accessioned2022-03-12T22:55:32Z
dc.date.available2022-03-12T22:55:32Z
dc.date.issued2021
dc.description.abstractIn the present study, a novel, eco-friendly, and simple polymeric adsorbent was obtained from cellulose acetate butyrate (CAB) and cysteine (Cys) to remove silver (I) ions in the presence of a thiol-ene click reaction under UV rays. Accordingly, firstly, CAB was modified with acrylate groups to turn it into a photocurable resin. Then, the acrylate modified CAB obtained with the monomer having cysteine and triacrylate group was crosslinked by thiol-ene click reaction under UV rays to obtain an eco-friendly adsorbent. The adsorbent acquired -S-, -COO and -NH2 groups as a result of this reaction and these functional groups are known to have the ability to selectively couple with Ag(I) ions. The adsorbent was evaluated for the selective removal of Ag(I) ions from aqueous samples characterized by SEM, SEM-EDAX, and FTIR. To determine the most suitable conditions, the effect of important parameters such as pH and contact time was investigated. It was determined that the most suitable isotherm for adsorption was the Langmuir isotherm (R: 0.999). The efficacy of our eco-friendly adsorbent was investigated in a real stream and lake waters and very good results were achieved. [GRAPHICS] .
dc.identifier.doi10.1007/s10570-021-03932-5
dc.identifier.eissn1572-882X
dc.identifier.issn0969-0239
dc.identifier.urihttps://hdl.handle.net/11424/236770
dc.identifier.wosWOS:000652934800001
dc.language.isoeng
dc.publisherSPRINGER
dc.relation.ispartofCELLULOSE
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectEnvironmental samples
dc.subjectSilver
dc.subjectEco-friendly adsorbent
dc.subjectThiol-ene photocurable adsorbent
dc.subjectL-cysteine
dc.subjectSOLID-PHASE EXTRACTION
dc.subjectENVIRONMENTAL-SAMPLES
dc.subjectAG I
dc.subjectADSORPTION
dc.subjectPRECONCENTRATION
dc.subjectNANOCOMPOSITE
dc.subjectMERCURY(II)
dc.subjectPOLYMER
dc.subjectNICKEL
dc.subjectGOLD
dc.titleCellulose/cysteine based thiol-ene UV cured adsorbent: removal of silver (I) ions from aqueous solution
dc.typearticle
dspace.entity.typePublication
local.avesis.id4a514525-e2ec-4a9e-9160-239dcf874af0
local.import.packageSS17
local.indexed.atWOS
local.indexed.atSCOPUS
local.journal.numberofpages10
oaire.citation.endPage6448
oaire.citation.issue10
oaire.citation.startPage6439
oaire.citation.titleCELLULOSE
oaire.citation.volume28
relation.isAuthorOfPublication8d9b57ea-628b-4e8c-a8e3-440b6aa8405d
relation.isAuthorOfPublication.latestForDiscovery8d9b57ea-628b-4e8c-a8e3-440b6aa8405d

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