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Properties of Thiol-ene Photocurable Highly Hydrophobic and Oleophobic Nanocomposite Coatings on ABS and HIPS Substrates

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dc.contributor.authorÇAKMAKÇI, EMRAH
dc.contributor.authorsMulazim, Yusuf; Cakmakci, Emrah; Kahraman, Memet V.
dc.date.accessioned2022-03-12T18:08:37Z
dc.date.available2022-03-12T18:08:37Z
dc.date.issued2013
dc.description.abstractIn this study, thiolene photocurable highly hydrophobic and oleophobic coatings were prepared and characterized. Trimethylolpropane tris(3-mercaptopropionate) and triallyl 1,3,5-triazine-2,4,6(1H,3H,5H)-trione were used for the preparation of the base formulation. Highly hydrophobic and oleophobic coatings were prepared with the aid of a fluorinated acrylate (Fluowet AC 812) and hydrophobic-fumed nanosilica particles. Nanoparticles were added for increasing the surface roughness and also to increase thermal and mechanical properties of the coatings. Coatings were applied on ABS (acrylonitrilebutadienestyrene) and HIPS (high impact polystyrene) substrates. As the fluorine and nanosilica contents were increased in the formulations, flame retardancy, hydrophobicity, and the oleophobicity of the coatings increased. Coatings were found to be highly thermally stable, highly solvent, and chemically resistant. The surface roughness of the coatings increased with the addition of hydrophobic-fumed nanosilica particles. In addition, the relation between the surface energy and the contact angle of the coatings was investigated. (c) 2012 Wiley Periodicals, Inc. Adv Polym Techn 32: E416E426, 2013; View this article online at wileyonlinelibrary.com. DOI 10.1002/adv.21289
dc.identifier.doi10.1002/adv.21289
dc.identifier.eissn1098-2329
dc.identifier.issn0730-6679
dc.identifier.urihttps://hdl.handle.net/11424/231176
dc.identifier.wosWOS:000316905900032
dc.language.isoeng
dc.publisherWILEY-HINDAWI
dc.relation.ispartofADVANCES IN POLYMER TECHNOLOGY
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectCoatings
dc.subjectHydrophobe
dc.subjectRadical polymerization
dc.subjectSilicas
dc.subjectThiolene
dc.subjectSURFACE MODIFICATION
dc.subjectPHOTOPOLYMERIZATION
dc.subjectKINETICS
dc.subjectMONOMERS
dc.subjectSYSTEMS
dc.subjectRESIN
dc.subjectFILMS
dc.subjectWATER
dc.titleProperties of Thiol-ene Photocurable Highly Hydrophobic and Oleophobic Nanocomposite Coatings on ABS and HIPS Substrates
dc.typearticle
dspace.entity.typePublication
local.avesis.ida1f94652-5074-4594-bff0-9092e2fd6fab
local.import.packageSS17
local.indexed.atWOS
local.indexed.atSCOPUS
local.journal.numberofpages11
oaire.citation.endPageE426
oaire.citation.startPageE416
oaire.citation.titleADVANCES IN POLYMER TECHNOLOGY
oaire.citation.volume32
relation.isAuthorOfPublication332869cd-e8a9-40ac-b678-cf5b01c6a6dc
relation.isAuthorOfPublication.latestForDiscovery332869cd-e8a9-40ac-b678-cf5b01c6a6dc

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