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Synthesis, characterization, photophysics, and photochemistry of peripherally substituted tetrakis(quinolinylethylenephenoxy)-substituted zinc(ii) phthalocyanines

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dc.contributor.authorYALÇIN, BAHATTİN
dc.contributor.authorsOzdemir, Mucahit; Artuc, Gamze Ozgul; Akkurt, Barbaros; Yalcin, Bahattin; Satan, Umit; Durmus, Mahmut; Bulut, Mustafa
dc.date.accessioned2022-03-12T22:58:11Z
dc.date.available2022-03-12T22:58:11Z
dc.date.issued2021
dc.description.abstractIn this work, 2-chloro-6-methoxyquinoline-3-carbaldehyde was reacted with [4-(3,4-dicyanophenoxy)phenyl]acetic acid to obtain 2-(3,4-dicyanophenoxy)phenyl-4-(2-chloro-6-methoxyquinolin-3-yl)-3-butenoic acid as a phthalocyanine precursor. This compound was heated in 2-dimethylaminoethanol in the presence of zinc acetate to yield 2,9(10),16(17),23(24)-tetrakis[2-phenoxy-4-(2-chloro-6-methoxyquinolin-3-yl)-3-butenoic acid] substituted zinc(ii) phthalocyanine. Some thiols, namely n-butanethiol (R-1), n-hexanethiol (R-2), 3-sulfanylpropionic acid (R-3), and 7-sulfanyl-2H-1-benzopyran-2-one (R-4), were reacted with this zinc(ii) phthalocyanine compound. Nucleophilic aromatic substitution reaction occurred at the chloro substituent of the respective quinoline on the phthalocyanine framework. The fluorescence behavior, singlet oxygen generation, and photostability properties of these novel phthalocyanines were investigated. These compounds may be potential photosensitizers for photodynamic therapy and deserve further study.
dc.identifier.doi10.1039/d1nj00854d
dc.identifier.eissn1369-9261
dc.identifier.issn1144-0546
dc.identifier.urihttps://hdl.handle.net/11424/237154
dc.identifier.wosWOS:000651421700001
dc.language.isoeng
dc.publisherROYAL SOC CHEMISTRY
dc.relation.ispartofNEW JOURNAL OF CHEMISTRY
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectLANGMUIR-BLODGETT-FILMS
dc.subjectPHOTODYNAMIC THERAPY
dc.subjectMETAL-FREE
dc.subjectALUMINUM PHTHALOCYANINE
dc.subjectPHOTOVOLTAIC PROPERTIES
dc.subjectIN-VITRO
dc.subjectCOUMARIN
dc.subjectPHOTOSENSITIZERS
dc.subjectMOIETIES
dc.titleSynthesis, characterization, photophysics, and photochemistry of peripherally substituted tetrakis(quinolinylethylenephenoxy)-substituted zinc(ii) phthalocyanines
dc.typearticle
dspace.entity.typePublication
local.avesis.idc0abf54d-ecf1-4beb-8b25-4092b04c06e6
local.import.packageSS17
local.indexed.atWOS
local.indexed.atSCOPUS
local.journal.numberofpages10
oaire.citation.endPage9921
oaire.citation.issue22
oaire.citation.startPage9912
oaire.citation.titleNEW JOURNAL OF CHEMISTRY
oaire.citation.volume45
relation.isAuthorOfPublication6405e2ff-5dd8-487d-a639-ac5fcc0832bc
relation.isAuthorOfPublication.latestForDiscovery6405e2ff-5dd8-487d-a639-ac5fcc0832bc

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