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Dual-curable PVB based adhesive formulations for cord/rubber composites: The influence of reactive diluents

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dc.contributor.authorYILDIZ, ZEHRA
dc.contributor.authorsYildiz, Zehra; Onen, Hacer Aysen
dc.date.accessioned2022-03-12T20:32:13Z
dc.date.available2022-03-12T20:32:13Z
dc.date.issued2017
dc.description.abstractIn this study, the effects of reactive diluent type on the adhesion strength of cord/rubber surfaces were investigated. For this purpose, a urethane acrylate oligomer was synthesized by the reaction of 2,4-toluene diisocyanate (TDI), 2-hydroxyethyl methacrylate (HEMA) and polyvinyl butyral (PVB) in the presence of di-n-butyltin dilaurate (T12) as catalyst. The structure of the oligomer was characterized by nuclear magnetic resonance (NMR) spectroscopy. Then the oligomer was included in adhesive formulations together with trimethylolpropane trimethacrylate (TMPTMA) and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents and thermal and photo initiator respectively. Polyester/polyamide cord fabrics were dipped into the adhesive solution and cured by UV-light. Then coated fabrics were characterized by Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). Contact angle measurement was employed to investigate the wettability properties of the coated fabrics. Thermal curing between the coated fabric and rubber was performed under heat and pressure. The adhesion strength between the cord/rubber surfaces was determined by T-peel test. The highest adhesion strength of 100.4 N/cm with the lowest contact angle value of 70.2 were obtained in the sample containing TCDDA as reactive diluent, due to a higher functionality resulting in a greater crosslinking density.
dc.identifier.doi10.1016/j.ijadhadh.2017.06.004
dc.identifier.eissn1879-0127
dc.identifier.issn0143-7496
dc.identifier.urihttps://hdl.handle.net/11424/234373
dc.identifier.wosWOS:000412259100006
dc.language.isoeng
dc.publisherELSEVIER SCI LTD
dc.relation.ispartofINTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectUV-curing
dc.subjectAdhesion
dc.subjectPolyvinyl butyral
dc.subjectReactive diluent
dc.subjectCord fabric
dc.subjectPOLYETHYLENE TEREPHTHALATE
dc.subjectPOLYURETHANE ACRYLATE
dc.subjectRUBBER
dc.subjectPOLYMERIZATION
dc.subjectDERIVATIVES
dc.subjectSYSTEM
dc.subjectFILMS
dc.subjectRESORCINOL
dc.subjectSTABILITY
dc.subjectMONOMERS
dc.titleDual-curable PVB based adhesive formulations for cord/rubber composites: The influence of reactive diluents
dc.typearticle
dspace.entity.typePublication
local.avesis.id24ce424b-2c06-44cb-83c1-61b93411ac0f
local.import.packageSS17
local.indexed.atWOS
local.indexed.atSCOPUS
local.journal.numberofpages7
local.journal.quartileQ2
oaire.citation.endPage44
oaire.citation.startPage38
oaire.citation.titleINTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
oaire.citation.volume78
relation.isAuthorOfPublicationcb7c7d31-1853-4b87-8cc4-4e0fc7d25db7
relation.isAuthorOfPublication.latestForDiscoverycb7c7d31-1853-4b87-8cc4-4e0fc7d25db7

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