Publication:
Flame retardance of epoxy acrylate resin modified with phosphorus containing compounds

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dc.contributor.authorKAHRAMAN, MEMET VEZİR
dc.contributor.authorsKahraman, MV; Kayaman-Apohan, N; Arsu, N; Gungor, A
dc.date.accessioned2022-03-10T15:24:58Z
dc.date.available2022-03-10T15:24:58Z
dc.date.issued2004
dc.description.abstractIn this work, UV radiation curing of allyldiphenyl phosphine oxide (ADPPO) and 4,4'-bis(allyloxyphenyl) phenyl phosphine oxide (DAPPO) monomers with epoxy acrylate resin in the presence of a photoinitiator was studied and their flame-retardant performance compared with pure epoxy acrylate film. The structures of allyl functional phosphorus compounds were characterized by FT-IR, H-1 NMR, C-13 NMR and all spectra were consistent with the expected structures. The polymerization behavior of both allyl functional monomers was followed in detail by monitoring the disappearance of acrylate and allyl groups by real-time infrared spectroscopy. It was obtained that the reactivity of DAPPO monomer is higher than ADPPO. In the case of ADPPO, chain transfer to monomer basically predominates. In each monomer, a tack free coating was obtained immediately upon irradiation. The addition of DAPPO leads to an improvement of the thermal and flame-retardant properties of the polymeric films. Thermal gravimetric analysis of DAPPO containing polymeric films gave higher char yield compared with UV cured pure epoxy acrylate resin. (C) 2004 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.porgcoat.2004.07.014
dc.identifier.eissn1873-331X
dc.identifier.issn0300-9440
dc.identifier.urihttps://hdl.handle.net/11424/220036
dc.identifier.wosWOS:000224964600007
dc.language.isoeng
dc.publisherELSEVIER SCIENCE SA
dc.relation.ispartofPROGRESS IN ORGANIC COATINGS
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectUV-curing
dc.subjectphosphorus
dc.subjectflame retardance
dc.subjectallylic oligomers
dc.subjectkinetics
dc.subjectPOLYMERIZATION
dc.subjectKINETICS
dc.subjectOXIDE
dc.titleFlame retardance of epoxy acrylate resin modified with phosphorus containing compounds
dc.typereview
dspace.entity.typePublication
local.avesis.id3a8814f0-0fb8-4b96-a8d8-17fca66fb1a8
local.import.packageSS5
local.indexed.atWOS
local.indexed.atSCOPUS
local.journal.numberofpages7
oaire.citation.endPage219
oaire.citation.issue3
oaire.citation.startPage213
oaire.citation.titlePROGRESS IN ORGANIC COATINGS
oaire.citation.volume51
relation.isAuthorOfPublication7676f3ad-0384-4001-b17d-b928ae2de7e6
relation.isAuthorOfPublication.latestForDiscovery7676f3ad-0384-4001-b17d-b928ae2de7e6

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