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Preparation and Characterization of UV-Curable, Boron-Containing, Transparent Hybrid Coatings

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dc.contributor.authorKAHRAMAN, MEMET VEZİR
dc.contributor.authorsMulazim, Yusuf; Kahraman, Memet Vezir; Apohan, Nilhan Kayaman; Kiziltas, Sahip; Gungor, Atilla
dc.date.accessioned2022-03-12T17:52:26Z
dc.date.available2022-03-12T17:52:26Z
dc.date.issued2011
dc.description.abstractA series of ultraviolet (UV)-curable, boron-containing hybrid coatings were prepared by an anhydrous sol-gel technique from a mixture of an acrylated bisphenol A based epoxy resin, methacryloxymethyl triethoxysilane, and boric acid. The use of boric acid allowed the hydrolysis and condensation of hybrid silicon alkoxides without the further addition of water or a catalyst. The chemical structure of the boron-containing hybrid coatings was characterized with Fourier transform infrared, real-time infrared, and Si-29 cross-polarization/magic-angle spinning NMR techniques. UV-curable coatings were applied to polycarbonate and Plexiglas substrates. The physical and mechanical properties of the UV-cured coatings (e.g., pendulum hardness, pencil hardness, con-tact angle, gel content, methyl ethyl ketone rubbing test, tensile test, abrasion resistance, chemical resistance, neutron absorption, and limiting oxygen index) were examined. The hybrid coatings showed a significant enhancement in their radiation-shielding properties. The thermal behavior of the coatings was also evaluated. It was observed that the thermal stability of the coatings mainly depended on their boron and silicate contents. The results of all analyses of the free films and coatings were examined. VC 2010 Wiley Periodicals, (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 120: 2112-2121, 2011
dc.identifier.doi10.1002/app.33358
dc.identifier.eissn1097-4628
dc.identifier.issn0021-8995
dc.identifier.urihttps://hdl.handle.net/11424/230402
dc.identifier.wosWOS:000288337400030
dc.language.isoeng
dc.publisherWILEY
dc.relation.ispartofJOURNAL OF APPLIED POLYMER SCIENCE
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectcoatings
dc.subjectcrosslinking
dc.subjectflame retardance
dc.subjectirradiation
dc.subjectneutron reflectivity
dc.subjectFLAME-RETARDANT THERMOSETS
dc.subjectSOL-GEL PROCESS
dc.subjectBISPHENOL
dc.subjectOLIGOMERS
dc.subjectACRYLATE
dc.subjectPOLYMER
dc.subjectRESINS
dc.subjectACID
dc.titlePreparation and Characterization of UV-Curable, Boron-Containing, Transparent Hybrid Coatings
dc.typearticle
dspace.entity.typePublication
local.avesis.id8d2fcebb-5d4a-4d02-8950-bce85ebfd004
local.import.packageSS17
local.indexed.atWOS
local.indexed.atSCOPUS
local.journal.numberofpages10
oaire.citation.endPage2121
oaire.citation.issue4
oaire.citation.startPage2112
oaire.citation.titleJOURNAL OF APPLIED POLYMER SCIENCE
oaire.citation.volume120
relation.isAuthorOfPublication7676f3ad-0384-4001-b17d-b928ae2de7e6
relation.isAuthorOfPublication.latestForDiscovery7676f3ad-0384-4001-b17d-b928ae2de7e6

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