Publication:
Vegetable oil-based, coumarin-containing antibacterial thermosets with improved thermal stability via copper-free thermal azide-alkyne click polymerization

Simple item page
dc.contributor.authorÇAKMAKÇI, EMRAH
dc.contributor.authorÖZDEMİR, MÜCAHİT
dc.contributor.authorYALÇIN, BAHATTİN
dc.contributor.authorsÇAKMAKÇI E., Ozdemir M., Sen F., Bulut M., YALÇIN B.
dc.date.accessioned2023-04-03T10:26:18Z
dc.date.available2023-04-03T10:26:18Z
dc.date.issued2022-08-01
dc.description.abstractIn recent years, the preparation of thermoset materials based on renewable sources has received peculiar attention. In this work, we prepared vegetable oil based antibacterial thermosets via thermal azide-alkyne cycloaddition reactions. Dimer diamine was propargylated and mixed with azidated trimethylolpropane triglycidyl ether and castor oil bearing azide and phosphorous groups. Two different propargyl functionalized marins were also incorporated into the vegetable oil based formulations. All synthesized monomers characterized by Fourier-transform infrared (FTIR) and Nuclear magnetic resonance (NMR) spectroscopy. chanical, thermal and antibacterial properties of the obtained thermosets were also determined. The thermosets behaved as elastomers and displayed elongation at break values between 39% and 82%. The phosphorylated castor oil derivative improved the thermal properties and char yields as high as 13.83% at 750 ? were observed under nitrogen atmosphere. Coumarin-containing thermosets were found to have antibacterial activity against both gram-positive and gram-negative bacteria.
dc.identifier.citationÇAKMAKÇI E., Ozdemir M., Sen F., Bulut M., YALÇIN B., "Vegetable oil-based, coumarin-containing antibacterial thermosets with improved thermal stability via copper-free thermal azide-alkyne click polymerization", INDUSTRIAL CROPS AND PRODUCTS, cilt.182, 2022
dc.identifier.doi10.1016/j.indcrop.2022.114870
dc.identifier.issn0926-6690
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0926669022003533?via%3Dihub
dc.identifier.urihttps://hdl.handle.net/11424/288081
dc.identifier.volume182
dc.language.isoeng
dc.relation.ispartofINDUSTRIAL CROPS AND PRODUCTS
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectTarımsal Bilimler
dc.subjectZiraat
dc.subjectToprak ve Bitki Besleme
dc.subjectToprak Verimliliği ve Gübreleme
dc.subjectAgricultural Sciences
dc.subjectAgriculture
dc.subjectSoil and Plant Feed
dc.subjectSoil Fertility, Acidity, Alkanility
dc.subjectZİRAAT MÜHENDİSLİĞİ
dc.subjectTarım Bilimleri
dc.subjectTarım ve Çevre Bilimleri (AGE)
dc.subjectTARIM BİLİMİ
dc.subjectAGRICULTURAL ENGINEERING
dc.subjectAGRICULTURAL SCIENCES
dc.subjectAgriculture & Environment Sciences (AGE)
dc.subjectAGRONOMY
dc.subjectAgronomi ve Mahsul Bilimi
dc.subjectGenel Tarım ve Biyoloji Bilimleri
dc.subjectYaşam Bilimleri
dc.subjectAgronomy and Crop Science
dc.subjectGeneral Agricultural and Biological Sciences
dc.subjectLife Sciences
dc.subjectCastor oil
dc.subjectDimer diamine
dc.subjectAzide-alkyne click reaction
dc.subjectPhosphorus
dc.subjectCoumarin
dc.subjectAntibacterial
dc.subjectEPOXY THERMOSETS
dc.subjectFLAME-RETARDANT
dc.subjectSOYBEAN OIL
dc.subjectCASTOR-OIL
dc.subjectCHEMISTRY
dc.subjectDERIVATIVES
dc.subjectISOSORBIDE
dc.subjectPOLYMERS
dc.subjectCOATINGS
dc.subjectRESINS
dc.subjectCastor oil
dc.subjectDimer diamine
dc.subjectAzide-alkyne click reaction
dc.subjectPhosphorus
dc.subjectCoumarin
dc.subjectAntibacterial
dc.titleVegetable oil-based, coumarin-containing antibacterial thermosets with improved thermal stability via copper-free thermal azide-alkyne click polymerization
dc.typearticle
dspace.entity.typePublication
local.avesis.id257deb81-a573-4ded-a22b-84a17d311e9c
local.indexed.atWOS
local.indexed.atSCOPUS
relation.isAuthorOfPublication332869cd-e8a9-40ac-b678-cf5b01c6a6dc
relation.isAuthorOfPublication8ce578f0-69d2-471b-ae61-0d2526613f8f
relation.isAuthorOfPublication6405e2ff-5dd8-487d-a639-ac5fcc0832bc
relation.isAuthorOfPublication.latestForDiscovery332869cd-e8a9-40ac-b678-cf5b01c6a6dc

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
7.pdf
Size:
4.35 MB
Format:
Adobe Portable Document Format
Download

Collections

Research Outputs