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AYDEMİR, CEM

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AYDEMİR

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CEM

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Now showing 1 - 5 of 5
  • PublicationOpen Access
    Sustainability in the print and packaging industry
    (2023-07-01) TUTAK, DOĞAN; AYDEMİR, CEM; YENİDOĞAN, SEMİHA; Tutak D., Aydemir C., Yenidoğan S.
    In the printing and packaging industry, sustainability is defined as manufacture and practices that reflect responsibility for the environment and resources to meet the needs and expectations of future generations. In this article, raw material management, cellulose resources, industrial forests, ecological and renewable alternative fiber resources were examined in the framework of the sustainability of the printing and packaging industry. The recycling of printed materials and packaging and the effects of paper-ink types and product design in this recycling have been discussed. The effect of separation and processing at the source on the efficiency of paper recycling, economy and ecology was emphasized. The greenhouse gas emissions of solvents used in inks and cleaners, the impact on climate change, water footprint and carbon footprint issues were examined. Suggestions have been made on environmental sustainability in the printing industry, what needs to be done for a competitive production, successful optimization, minimization of waste, use of existing possibilities, recycling and evaluation of alternatives and use of clean energy.
  • Publication
    The use of natural (Pinus pinaster) resin in the production of printing ink and the printability effect
    (WILEY, 2020) AYDEMİR, CEM; Karademir, Arif; Aydemir, Cem; Yenidogan, Semiha; Arman Kandirmaz, Emine; Kiter, Rukiye G.
    Alkyd resins are generally used in the production of printing inks. All industries look for alternative raw materials in the production of ink with the growing inclination toward using natural products. Resins forming the vehicle of the ink to be obtained from natural resources will provide benefits for the environment, nature, and living creatures. The aim of the study was to promote the use of natural resin in the ink system. NaturalPinus pinasterresin was added into vegetable and mineral oil-based solvents in pure form with alkyd resin in different amounts and ink varnishes of different combinations were prepared. Then, printing inks were produced from these varnishes in pure and hybrid form. Following the assessment of the rheological properties of the inks prepared, printing tests were conducted to assess the printing quality parameters. Ideal mixing ratios of the natural resins in the ink were determined for printability. The environmental importance and advantages of the use of natural resins were discussed. Recommendations were given in line with the results to encourage widespread use of natural resins in near future.
  • PublicationOpen Access
    Controlling unequal surface energy results caused by test liquids: the case of UV/O3 Treated PET
    (2022-04-01) AYDEMİR, CEM; Altay B. N., Fleming P. D., Rahman M. A., Pekarovicova A., Myers B., AYDEMİR C., KARADEMİR A.
    Ultraviolet/ozone (UV/O-3) treatment has been reported to be an effective method to modify properties such as wettability, adhesion or adsorption of plastic surfaces. The change in the surface is measured by contact angle analysis, which employs liquids and their surface tensions (ST) to estimate the surface energy (SE). We found two different practices in the scientific community: (1) the majority of researchers adopted the ST value of liquids from the literature, while (2) other researchers conducted real-time measurements in the lab under ambient conditions prior to SE estimation. To the best of our knowledge, there is no study that compares the difference between the two practices. One study was found to show different SE methods generating unequal SE values for the same substrate. However, there was no definitive conclusion backed by general thermodynamics rules. In this study, we presented (1) a statistical significance test that showed the literature and experimental ST values are significantly different, and studied (2) the effect of different liquid pairs on the SE estimation for UV/O-3 treated poly(ethylene terephthalate) (PET) substrate. Modification techniques such as atmospheric pressure plasma or chemical modification were studied previously to examine PET\"s wettability and the SE. The UV/O-3 treatment was studied to improve adhesion and to modify its chemical properties for adsorption. In contrast, we studied (3) the effect of UV/O-3 on wettability at different timeframes and addressed (4) how to control unequal SE based on a method that was refined on a rigorous thermodynamic three-phase system. It must be noted that this method can be generalized to other types of solid surfaces to estimate thermodynamically self-consistent SE values. This work also provides (5) a web-based calculator that complements computational findings available to the readership in the data availability section.
  • PublicationOpen Access
    Starch-based nanoparticles as a replacement for synthetic latex: A comprehensive assessment of printability and colorimetric characteristics
    (2024-01-01) AYDEMİR, CEM; Altay B. N., Carver-Kubik A., Williams S., Huq A., Sugiyama M., Dhote Y., Zunjarrao A., AYDEMİR C., Karademir A.
    The papermaking, packaging, and printing industry are actively seeking sustainable material alternatives to address growing concerns about environmental consciousness and finite resources. Synthetic latex, a frequently utilized binder in paper coating formulations, present difficulties due to their dependence on fossil fuel resources and their reduced recyclability in comparison to eco-friendly sustainable products. In this study, synthetic latex was replaced with a starch-based nanoparticle (starch NP) binder at a 1:1 ratio in a coating formulation. Printing trials to assess colorimetric characteristics was made using electrophotography (EP) printing, given the current upward trajectory and expansion of EP technology into the label, packaging, and folding carton sectors. The in-depth investigations reveal that incorporating starch NP binder result in improved optical, color, and dot characteristics. Moreover, it maintains consistent and comparable coefficients of friction. Partial replacement of synthetic latex with the starch NP binder yields significant enhancements in surface roughness and text quality. Importantly, the starch NP binder not only improves the dielectric relaxation properties of the paper and enhances toner transfer but also accelerates the distribution of the electrical field compared to synthetic latex, optimizing toner transfer and thereby enhancing color gamut volume. The study demonstrates that employing the starch NP binder leads to substantial improvements in colorimetric performance without any drawbacks in EP printing, making it highly advantageous to replace 50% of the synthetic binder.
  • Publication
    Surface analysis of polymer films for wettability and ink adhesion
    (WILEY, 2021) AYDEMİR, CEM; Aydemir, Cem; Altay, Bilge Nazli; Akyol, Merve
    The interaction between inks and substrates is critical during printing. Adhesion of the ink film is determined by the reciprocal interactions of polar and nonpolar (dispersive) components between polymer films and inks. The greater the similarity between the polar and dispersive components of inks, coating and substrates, the better the wetting and adhesion on the surface of printing substrate. Various liquid materials in printing such as inks, varnishes, lacquers, and adhesives contain high ratios of water. The highly polar nature of water makes the interaction of these materials unsuitable with predominantly disperse polymer surfaces. Some films with polyolefin structure, especially polypropylene, and polyethylene, are nonpolar and cannot form strong bonds with ink, varnish, or lacquer coatings due to their chemical structure. Increasing surface energy components overcomes the poor wetting and adhesion on polymer surfaces. In this review, the topics of water contact angle measurement and determination of surface energy, surface tension, and using sessile drop method for the wettability and ink adhesion of polymer films are surveyed. Information on structural and chemical processes was given that assists in obtaining wettable film surfaces. Recommendations were made for good adhesion and printability based on surface treatment methods and ink modification.