Publication:
Hydroxylation of pendant vinyl groups of poly(3-hydroxy undec-10-enoate) in high yield

Simple item page
dc.contributor.authorEROĞLU, MEHMET SAYIP
dc.contributor.authorsEroglu, MS; Hazer, B; Ozturk, T; Caykara, T
dc.date.accessioned2022-03-12T17:22:47Z
dc.date.accessioned2026-01-10T20:35:57Z
dc.date.available2022-03-12T17:22:47Z
dc.date.issued2005
dc.description.abstractPoly(3-hydroxy undec-10-enoate) (PHU) was synthesized by feeding Pseudomonas oleovarans with 10-undecenoic acid and nearly 100%, hydroxylation of double bonds of PHU was achieved by hydroboration-oxidation reaction using 9-borobicyclononane. The disappearance of vinyl signals of PHU in proton and C-13 NMR spectra was observed. Acetylation of hydroxylated PHU was conducted for molecular weight measurements. Molecular weight and polydispersity of hydroxylated PHU were found to be 10,000 and 1.23, respectively, while that of the originals was 32,000 and 2.42. Decomposition temperatures of original and hydroxylated PHU were 280 and 200 degrees C, respectively. (C) 2005 Wiley Periodicals, Inc.
dc.identifier.doi10.1002/app.21943
dc.identifier.issn0021-8995
dc.identifier.urihttps://hdl.handle.net/11424/228446
dc.identifier.wosWOS:000230802900047
dc.language.isoeng
dc.publisherWILEY-BLACKWELL
dc.relation.ispartofJOURNAL OF APPLIED POLYMER SCIENCE
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectPHU
dc.subjectPHAs
dc.subjectbiopolyesters
dc.subjectUNSATURATED SIDE-CHAINS
dc.subjectBACTERIAL POLYESTERS
dc.subjectPSEUDOMONAS-OLEOVORANS
dc.subjectCROSS-LINKING
dc.subjectEPOXIDATION
dc.subjectPOLY-3-HYDROXYALKANOATES
dc.subjectBIOSYNTHESIS
dc.subjectACIDS
dc.subjectUNITS
dc.titleHydroxylation of pendant vinyl groups of poly(3-hydroxy undec-10-enoate) in high yield
dc.typearticle
dspace.entity.typePublication
oaire.citation.endPage2139
oaire.citation.issue5
oaire.citation.startPage2132
oaire.citation.titleJOURNAL OF APPLIED POLYMER SCIENCE
oaire.citation.volume97

Files

Collections

Araştırma Çıktıları