Publication:
Electrocatalytic Performances of Carbon Supported Metallophthalocyanine and Pt/Metallophthalocyanine Catalysts Towards Dioxygen Reduction in Acidic Medium

dc.contributor.authorÖZKAYA, ALİ RIZA
dc.contributor.authorsKoc, I.; Camur, M.; Bulut, M.; Ozkaya, A. R.
dc.date.accessioned2022-03-12T17:35:56Z
dc.date.accessioned2026-01-11T14:20:41Z
dc.date.available2022-03-12T17:35:56Z
dc.date.issued2009
dc.description.abstractElectrocatalytic performances of phthalocyanines (Pcs) involving N-benzyl-4-phenyloxyacetamide moieties, dispersed on a high-surface area carbon substrate, Vulcan XC-72 (VC) and Nafion (Nf), towards oxygen reduction in acidic medium were determined and compared. The VC/Nf/CoPc(5) catalyst showed much higher catalytic activity than those of the other Pc(1-4)-based catalysts (H2Pc 1, ZnPc 2, NiPc 3 and CuPc 4) and that of unsubstituted CoPc-based one. The comparison of the performance of VC/Nf/Pt-5 dual catalyst with that of VC/Nf/Pt one indicated that the former can be a good alternative to the latter as a cathode catalyst both in direct methanol and H-2/O-2 fuel cell applications.
dc.identifier.doi10.1007/s10562-009-0075-z
dc.identifier.eissn1572-879X
dc.identifier.issn1011-372X
dc.identifier.urihttps://hdl.handle.net/11424/229222
dc.identifier.wosWOS:000269883300006
dc.language.isoeng
dc.publisherSPRINGER
dc.relation.ispartofCATALYSIS LETTERS
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectPhthalocyanines
dc.subjectPlatinum
dc.subjectOxygen reduction
dc.subjectElectrocatalysis
dc.subjectMethanol tolerant catalyst
dc.subjectMETAL TETRASULFONATED PHTHALOCYANINES
dc.subjectHIGH-AREA CARBON
dc.subjectOXYGEN-REDUCTION
dc.subjectHYDROGEN-PEROXIDE
dc.subjectCOBALT PHTHALOCYANINES
dc.subjectO-2 REDUCTION
dc.subjectELECTROREDUCTION
dc.subjectMETHANOL
dc.subjectELECTROLYTE
dc.subjectSTABILITY
dc.titleElectrocatalytic Performances of Carbon Supported Metallophthalocyanine and Pt/Metallophthalocyanine Catalysts Towards Dioxygen Reduction in Acidic Medium
dc.typearticle
dspace.entity.typePublication
oaire.citation.endPage380
oaire.citation.issue3-4
oaire.citation.startPage370
oaire.citation.titleCATALYSIS LETTERS
oaire.citation.volume131

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