Publication:
Synthesis and characterization of novel azo-bridged Zn(II) and Co(II) bisphthalocyanines

dc.contributor.authorsYazici A., Ateş D., Bekaroǧlu Ö., Kobayashi N.
dc.date.accessioned2022-03-15T01:55:26Z
dc.date.accessioned2026-01-11T19:02:31Z
dc.date.available2022-03-15T01:55:26Z
dc.date.issued2006
dc.description.abstractMetal phthalocyanines containing an unsymmetrically substituted nitro group were synthesized from 4-nitrophthalonitrile and the corresponding anhydrous metal salts (Co(OAc)2, Zn(OAc)2) by the method of statistically mixed condensation reactions. The new type of metallobisphthalocyanine compounds connected by a N=N bridge was prepared from the reactions of respective nitro compounds with sodium hydroxide (NaOH) and activated zinc powder in a mixture of methanol (MeOH) and tetrahydrofuran (THF). The structures of these compounds were characterized by using 1H NMR, IR, elemental analyses, UV-vis and magnetic circular dichroism spectroscopies. Copyright © 2006 Society of Porphyrins & Phthalocyanines.
dc.identifier.doi10.1142/s1088424606000491
dc.identifier.issn10884246
dc.identifier.urihttps://hdl.handle.net/11424/246731
dc.language.isoeng
dc.publisherSociety of Porphyrins and Phthalocyanines (SPP)
dc.relation.ispartofJournal of Porphyrins and Phthalocyanines
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAzo bridge
dc.subjectCobalt
dc.subjectMagnetic circular dichroism
dc.subjectPhthalocyanine
dc.titleSynthesis and characterization of novel azo-bridged Zn(II) and Co(II) bisphthalocyanines
dc.typearticle
dspace.entity.typePublication
oaire.citation.endPage1144
oaire.citation.issue9-10
oaire.citation.startPage1140
oaire.citation.titleJournal of Porphyrins and Phthalocyanines
oaire.citation.volume10

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