Publication: Catalytic Activity of a Thermoregulated, Phase-Separable Pd(II)-perfluoroalkylphthalocyanine Complex in an Organic/Fluorous Biphasic System: Hydrogenation of Olefins
| dc.contributor.author | ÖZER, METİN | |
| dc.contributor.authors | Yilmaz, Filiz; Ozer, Metin; Kani, Ibrahim; Bekaroglu, Oezer | |
| dc.date.accessioned | 2022-03-12T17:46:50Z | |
| dc.date.accessioned | 2026-01-11T17:51:52Z | |
| dc.date.available | 2022-03-12T17:46:50Z | |
| dc.date.issued | 2009 | |
| dc.description.abstract | A fluoroalkene-soluble tetrakis[heptadecafluorononyl]-substituted Pd(II)-phthalocyanine complex has been studied for olefin (styrene, 1-octene, trans-2-octene and cyclohexene) hydrogenation with molecular hydrogen in an organic/fluorous biphasic system [n-hexane/perfluoromethyl cyclohexane (PFMCH)]. The palladium complex was found to be an active catalyst for styrene (100% conversion, TON = 634) and 1-octene (92%, TON = 596) at 80 degrees C and 15 bar of H-2 after 6 h of reaction time. The catalyst was recycled in nine consecutive reactions for the hydrogenation of styrene without the loss of activity or metal contamination. | |
| dc.identifier.doi | 10.1007/s10562-009-9959-1 | |
| dc.identifier.eissn | 1572-879X | |
| dc.identifier.issn | 1011-372X | |
| dc.identifier.uri | https://hdl.handle.net/11424/229571 | |
| dc.identifier.wos | WOS:000267330300055 | |
| dc.language.iso | eng | |
| dc.publisher | SPRINGER | |
| dc.relation.ispartof | CATALYSIS LETTERS | |
| dc.rights | info:eu-repo/semantics/closedAccess | |
| dc.subject | Biphasic catalysis | |
| dc.subject | Hydrogenation | |
| dc.subject | Phthalocyanine | |
| dc.subject | Palladium complex | |
| dc.subject | Fluorous solvent | |
| dc.subject | FLUOROUS CATALYSIS | |
| dc.subject | OXIDATION | |
| dc.subject | PHTHALOCYANINE | |
| dc.subject | EPOXIDATION | |
| dc.subject | PORPHYRIN | |
| dc.subject | SOLVENTS | |
| dc.subject | ALKENES | |
| dc.subject | CONDENSATION | |
| dc.subject | CYCLOHEXANE | |
| dc.subject | POLYMERS | |
| dc.title | Catalytic Activity of a Thermoregulated, Phase-Separable Pd(II)-perfluoroalkylphthalocyanine Complex in an Organic/Fluorous Biphasic System: Hydrogenation of Olefins | |
| dc.type | article | |
| dspace.entity.type | Publication | |
| oaire.citation.endPage | 647 | |
| oaire.citation.issue | 3-4 | |
| oaire.citation.startPage | 642 | |
| oaire.citation.title | CATALYSIS LETTERS | |
| oaire.citation.volume | 130 |