Publication:
Electrochemical and spectroelectrochemical properties of thiadiazole substituted metallo-phthalocyanines

Simple item page
dc.contributor.authorKOCA, ATIF
dc.contributor.authorsDemirbas, Umit; Akyuz, Duygu; Barut, Burak; Bayrak, Riza; Koca, Atif; Kantekin, Halit
dc.date.accessioned2022-03-12T20:29:10Z
dc.date.available2022-03-12T20:29:10Z
dc.date.issued2016
dc.description.abstract4-Thiadiazole substituted phthalonitrile and peripherally tetra-substituted phthalocyanine Cu(II), Fe(II) and Ti(IV)O complexes have been synthesized for the first time. Electrochemical properties of these complexes were determined with voltammetric and in situ spectroelectrochemical measurements. CuPc has redox inactive Cu2+ center, therefore it gave three Pc based reduction and two Pc based oxidation processes. TiOPc and FePc complexes gave metal based redox processes in addition to Pc based redox reactions due to the redox activity of Ti4+O and Fe2+ metal centers. Although FePc also gave three reduction and two oxidation reactions, peak potentials of these processes are different than those of CuPc due to the different assignments of the redox reactions. TiOPc went to five reduction and one oxidation reactions. Assignments of the redox processes were carried out with in situ spectroelectrochemical measurements. Spectra and color of the electrogenerated redox species of the complexes were also determined with in situ spectroelectrochemical and in situ electrocolorimetric measurements. Distinct color differences between the electrogenerated redox species were observed, which indicated their possible electrochromic usages. (C) 2015 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.saa.2015.07.105
dc.identifier.issn1386-1425
dc.identifier.pubmed26291672
dc.identifier.urihttps://hdl.handle.net/11424/234036
dc.identifier.wosWOS:000365360700009
dc.language.isoeng
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD
dc.relation.ispartofSPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectThiadiazole
dc.subjectPhthalocyanine
dc.subjectMetallophthalocyanine
dc.subjectElectrochemistry
dc.subjectSpectroelectrochemistry
dc.subjectIRON(II) PHTHALOCYANINE
dc.subjectTITANYL PHTHALOCYANINES
dc.subjectFUNCTIONALIZED GRAPHENE
dc.subjectCOPPER
dc.subjectCOMPLEXES
dc.subjectMETALLOPHTHALOCYANINES
dc.subjectTITANIUM(IV)
dc.subjectMOIETIES
dc.subjectBEHAVIOR
dc.subjectZINC
dc.titleElectrochemical and spectroelectrochemical properties of thiadiazole substituted metallo-phthalocyanines
dc.typearticle
dspace.entity.typePublication
local.avesis.idd0f92547-4b6b-414a-96a9-c03e890eb0df
local.import.packageSS17
local.indexed.atWOS
local.indexed.atSCOPUS
local.indexed.atPUBMED
local.journal.numberofpages8
local.journal.quartileQ2
oaire.citation.endPage78
oaire.citation.startPage71
oaire.citation.titleSPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
oaire.citation.volume153
relation.isAuthorOfPublicationc2c7874b-59cc-4592-8dc8-885dff2628ea
relation.isAuthorOfPublication.latestForDiscoveryc2c7874b-59cc-4592-8dc8-885dff2628ea

Files

Collections

Research Outputs