Publication:
POSS-vinyl-urethane acrylate-based nanohybrid coating materials

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dc.contributor.authorABDURRAHMANOĞLU, SUZAN
dc.contributor.authorKARATAŞ, SEVİM
dc.contributor.authorsEren Y., Şen F., ABDURRAHMANOĞLU S., KARATAŞ S.
dc.date.accessioned2023-11-20T08:28:58Z
dc.date.available2023-11-20T08:28:58Z
dc.date.issued2023-01-01
dc.description.abstractThe effect of POSS-vinyl-heptaisobutyl-substituted (POSSV) compounds as an inorganic additive on the thermal and physical properties of nanohybrid coating materials based on urethane acrylate (UA) resin has been investigated. A diol compound obtained from the reaction of itaconic acid and 1,2-epoxy cyclohexane has been used to produce an UV curable epoxy-based urathane acrylate resin. Nanohybrid coating materials were obtained by curing the UA resin with UV radiation through the thiol–ene reaction, mixed with various amounts of POSSV compounds. The structure of the UA resin was characterized by Fourier-transform infrared spectroscopy and nuclear magnetic resonance spectroscopy techniques. The UV curing process was also studied by the double bond conversion method. Aggregation of the nanohybrid materials was determined by X-ray diffraction. The thermal, non-flammability, and thermomechanical properties of the samples were examined by thermogravimetric analysis, limiting oxygen index, and dynamic mechanical analysis techniques. Light transmittance of the samples was determined by UV–Vis spectrophotometry, and their morphological structure was determined by scanning electron microscopy. In addition, gel contents, swelling rates, hardness, adhesion, contact angles, and resistance to chemicals and solvents of the samples were examined. In conclusion, nanohybrid materials obtained from the synthesized UA resin and improved with POSSV additive can be used in the coating industry.
dc.identifier.citationEren Y., Şen F., ABDURRAHMANOĞLU S., KARATAŞ S., "POSS-vinyl-urethane acrylate-based nanohybrid coating materials", Journal of Coatings Technology and Research, 2023
dc.identifier.doi10.1007/s11998-023-00839-7
dc.identifier.issn1945-9645
dc.identifier.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85176010959&origin=inward
dc.identifier.urihttps://hdl.handle.net/11424/294975
dc.language.isoeng
dc.relation.ispartofJournal of Coatings Technology and Research
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectKimya Mühendisliği ve Teknolojisi
dc.subjectKimya
dc.subjectFizikokimya
dc.subjectTemel Bilimler
dc.subjectMühendislik ve Teknoloji
dc.subjectChemical Engineering and Technology
dc.subjectChemistry
dc.subjectPhysical Chemistry
dc.subjectNatural Sciences
dc.subjectEngineering and Technology
dc.subjectMühendislik, Bilişim ve Teknoloji (ENG)
dc.subjectTemel Bilimler (SCI)
dc.subjectMühendislik
dc.subjectMÜHENDİSLİK, KİMYASAL
dc.subjectKİMYA, FİZİKSEL
dc.subjectEngineering, Computing & Technology (ENG)
dc.subjectNatural Sciences (SCI)
dc.subjectENGINEERING
dc.subjectCHEMISTRY
dc.subjectENGINEERING, CHEMICAL
dc.subjectCHEMISTRY, PHYSICAL
dc.subjectGenel Kimya
dc.subjectFizik Bilimleri
dc.subjectYüzeyler ve Arayüzler
dc.subjectYüzeyler, Kaplamalar ve Filmler
dc.subjectKolloid ve Yüzey Kimyası
dc.subjectGeneral Chemistry
dc.subjectPhysical Sciences
dc.subjectSurfaces and Interfaces
dc.subjectSurfaces, Coatings and Films
dc.subjectColloid and Surface Chemistry
dc.subjectThiol–ene click
dc.subjectUrethane acrylate
dc.subjectUV-cured
dc.titlePOSS-vinyl-urethane acrylate-based nanohybrid coating materials
dc.typearticle
dspace.entity.typePublication
local.avesis.id913987e7-0804-4e39-ac72-c7bf73c5b971
local.indexed.atSCOPUS
relation.isAuthorOfPublicationc4f5249d-7638-47df-be54-950af42ffa85
relation.isAuthorOfPublication224247a0-eaeb-4dd7-b17a-3bd7fc36d248
relation.isAuthorOfPublication.latestForDiscoveryc4f5249d-7638-47df-be54-950af42ffa85

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